Issue 21, 1999

The structural characterisation of Ph3PSe(Ph)I. The first charge transfer (CT) complex of a tertiary phosphine containing a pseudohalogen

Abstract

The reaction of 2 mol equivalents of triphenylphosphine with diphenyldiselenyldiiodine (Ph2Se2I2) produces the charge transfer (CT) complex Ph3PSe(Ph)I in quantitative yield; this compound represents the first report of a CT complex of a tertiary phosphine that contains a pseudohalogen.

Supplementary files

Article information

Article type
Paper

Chem. Commun., 1999, 2159-2160

The structural characterisation of Ph3PSe(Ph)I. The first charge transfer (CT) complex of a tertiary phosphine containing a pseudohalogen

P. D. Boyle, S. M. Godfrey, C. A. McAuliffe, R. G. Pritchard and J. M. Sheffield, Chem. Commun., 1999, 2159 DOI: 10.1039/A906039A

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