Issue 19, 1999
From the journal:

Chemical Communications

Synthesis and structure of a thiolate-bridged nickel–iron complex: towards a mimic of the active site of NiFe-hydrogenase

Sian C. Davies,   David J. Evans,   David L. Hughes,   Steven Longhurst  and  J. Roger Sanders  

Abstract

The reaction, under carbon monoxide, of [Fe(NS3)(CO)]– [NS3 = N(CH2CH2S)33–] with [NiCl2(dppe)] gives the structurally characterised dinuclear thiolate-bridged complex [{Fe(NS3)(CO)2-S,S′}NiCl(dppe)], which has structural features similar to those of the active site of NiFe-hydrogenase.

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DOI
https://doi.org/10.1039/A905353K
Article type
Paper

Chem. Commun., 1999, 1935-1936

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Synthesis and structure of a thiolate-bridged nickel–iron complex: towards a mimic of the active site of NiFe-hydrogenase

S. C. Davies, D. J. Evans, D. L. Hughes, S. Longhurst and J. Roger Sanders, Chem. Commun., 1999, 1935 DOI: 10.1039/A905353K

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