Issue 18, 1999

Two-electron photoelimination reactions from edge-sharing bioctahedral dimolybdenum(III) complexes

Abstract

Dimolybdenum(III) edge-sharing bioctahedral (ESBO) complexes, Mo2X6(dtbppm)2 [dtbppm = bis(di(4-tert-butylphenyl)phosphinomethane), X= Cl, Br, I], photoreact when irradiated with near-UV light, cleanly producing the corresponding quadruple metal–metal bonded complexes, Mo2X4(dtbppm)2.

Article information

Article type
Paper

Chem. Commun., 1999, 1831-1832

Two-electron photoelimination reactions from edge-sharing bioctahedral dimolybdenum(III) complexes

B. J. Pistorio and D. G. Nocera, Chem. Commun., 1999, 1831 DOI: 10.1039/A904143E

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