Issue 17, 1999

The reaction of difluorodioxirane with caesium trifluoromethoxide

Abstract

The reaction of difluorodioxirane with caesium trifluoromethoxide in the presence of CsF forms CF3OOC(O)F and the new compounds CF3O(OCF2O)nOC(O)F (n = 1≡3); 13C labeling shows that the dioxirane undergoes ring opening at the O–O bond.

Article information

Article type
Paper

Chem. Commun., 1999, 1671-1672

The reaction of difluorodioxirane with caesium trifluoromethoxide

Q. Huang and D. D. DesMarteau, Chem. Commun., 1999, 1671 DOI: 10.1039/A904090K

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