Issue 14, 1999

Deprotonation of low-spin mononuclear iron(III)–hydroperoxide complexes give transient blue species assigned to high-spin iron(III)–peroxide complexes

Abstract

Purple iron(III)–hydroperoxide complex ions [Fe(Rtpen)(η1-OOH)]2+ can be reversibly deprotonated to give transient blue species showing spectroscopic properties consistent with iron(III)–peroxide complexes; a novel ferryl species is produced in MS/MS experiments with the iron(III) hydroperoxide ion.

Article information

Article type
Paper

Chem. Commun., 1999, 1313-1314

Deprotonation of low-spin mononuclear iron(III)–hydroperoxide complexes give transient blue species assigned to high-spin iron(III)–peroxide complexes

K. B. Jensen, C. J. McKenzie, L. Preuss Nielsen, J. Zacho Pedersen and H. Molina Svendsen, Chem. Commun., 1999, 1313 DOI: 10.1039/A902985K

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