Issue 15, 1999
From the journal:

Chemical Communications

Transformations of fac-Re(dmbpy)(CO)3(CO2H) in the presence of carbon dioxide (dmbpy=4,4′-dimethyl-2,2′-bipyridine)

Dorothy H. Gibson  and  Xiaolong Yin  

Abstract

Reactions of fac-Re(dmbpy)(CO)3(CO2H) 1 or fac, fac-Re(dmbpy)(CO)3(CO2)Re(dmbpy)(CO)3 2 with CO2, in DMSO or DMF containing small amounts of water, lead to the bicarbonato complex, fac-Re(dmbpy)(CO)3[OC(O)OH] 4; the formato complex, fac-Re(dmbpy)(CO)3(OCHO) 5, is not a major product in any of these reactions.

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Article information

DOI
https://doi.org/10.1039/A902453K
Article type
Paper

Chem. Commun., 1999, 1411-1412

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Transformations of fac-Re(dmbpy)(CO)3(CO2H) in the presence of carbon dioxide (dmbpy=4,4′-dimethyl-2,2′-bipyridine)

D. H. Gibson and X. Yin, Chem. Commun., 1999, 1411 DOI: 10.1039/A902453K

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