Issue 12, 1999
From the journal:

Chemical Communications

Formation of the bidentate [Ph2SNC(Me)N(H)] ligand by metal-assisted sulfimide addition to acetonitrile; X-ray crystal structure of [Pt(Ph2SNH)(Ph2SNC(Me)NH)Cl]Cl·MeCN

Paul F. Kelly  and  Alexandra M. Z. Slawin  

Abstract

In contrast to similar reactions of Cu, Co and Pd species, the platinum(II) complex [Pt(MeCN)2Cl2] reacts with Ph2SNH (ratio 1:2) in MeCN via a metal assisted addition of the sulfimide to the acetonitrile to give [Pt(Ph2SNH)(Ph2SNC(Me)NH)Cl]Cl·MeCN, the first example of a complex of the bidentate [Ph2SNC(Me)N(H)] ligand.

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/A901783F
Article type
Paper

Chem. Commun., 1999, 1081-1082

Permissions

Request permissions

Formation of the bidentate [Ph2SNC(Me)N(H)] ligand by metal-assisted sulfimide addition to acetonitrile; X-ray crystal structure of [Pt(Ph2SNH)(Ph2SNC(Me)NH)Cl]Cl·MeCN

P. F. Kelly and A. M. Z. Slawin, Chem. Commun., 1999, 1081 DOI: 10.1039/A901783F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements