Issue 12, 1999
From the journal:

Chemical Communications

Synthesis and structures of heterometallic trinuclear clusters [CpFe(CO)2]2(µ3-S2)W(CO)5 and Cp2Fe2(CO)3(µ-CO)(µ3-S)W(CO)5 and kinetic study of migration of the W(CO)5 moiety in the disulfido complex

Katsuaki Kuge,   Hiromi Tobita  and  Hiroshi Ogino  

Abstract

The reaction of CpFe(CO)2Br, NaSH and W(CO)5(THF) gave two Fe2W clusters, one with a µ3-S2 and the other with a µ3-S; in the former cluster W(CO)5 moiety migration on the disulfido ligand was observed by variable-temperature 1H NMR spectroscopy.

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Article information

DOI
https://doi.org/10.1039/A901660K
Article type
Paper

Chem. Commun., 1999, 1061-1062

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Synthesis and structures of heterometallic trinuclear clusters [CpFe(CO)2]2(µ3-S2)W(CO)5 and Cp2Fe2(CO)3(µ-CO)(µ3-S)W(CO)5 and kinetic study of migration of the W(CO)5 moiety in the disulfido complex

K. Kuge, H. Tobita and H. Ogino, Chem. Commun., 1999, 1061 DOI: 10.1039/A901660K

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