Issue 8, 1999

A simple route to multifunctional phosphide and amide donor sets; syntheses and structures of [{ButPAs(NMe2)2}K.pmdeta]2 and [{CyNAs(NMe2)2K}2]

Abstract

The syntheses of [ButPAs(NMe2)2K.pmedta]2 1 and [{CyNAs(NMe2)2K}2] 2 from the reactions of [As(NMe2)3] with ButPH2 and CyNH2, respectively, in the presence of potassiated bases exemplify a general approach to multifunctional secondary phosphide and amide anions containing variable sets of group 15 donor centres.

Supplementary files

Article information

Article type
Paper

Chem. Commun., 1999, 739-740

A simple route to multifunctional phosphide and amide donor sets; syntheses and structures of [{ButPAs(NMe2)2}K.pmdeta]2 and [{CyNAs(NMe2)2K}2]

M. A. Beswick, A. D. Hopkins, S. J. Kidd, Y. G. Lawson, P. R. Raithby, D. S. Wright, A. Bashall, M. McPartlin, A. Rothenberger and F. Stalke, Chem. Commun., 1999, 739 DOI: 10.1039/A901222B

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