Issue 8, 1999
From the journal:

Chemical Communications

Unprecedented nitrosyl-bridged double-A-frame triplatinum complexes, [Pt3(µ-triphosphine)2(µ-NO)2(RNC)2](BF4)4

Tomoaki Tanase,   Makiko Hamaguchi,   Rowshan Ara Begum,   Shigenobu Yano  and  Yasuhiro Yamamoto  

Abstract

Reaction of linear triplatinum complexes, linear-[Pt3(µ-dpmp)2(RNC)2](PF6)2 1, with an excess of [NO][BF4] afforded an unprecedented nitrosyl-bridged double-A-frame triplatinum complexes, [Pt3(µ-dpmp)2(µ-NO)2(RNC)2](BF4)4 [2a: R = 2,6-xylyl; 2b: R = 2,4,6-mesityl, dpmp = bis(diphenylphosphinomethyl)phenylphosphine], which were characterized by X-ray crystallographic analysis and extended Hückel MO calculations.

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Article information

DOI
https://doi.org/10.1039/A900302I
Article type
Paper

Chem. Commun., 1999, 745-746

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Unprecedented nitrosyl-bridged double-A-frame triplatinum complexes, [Pt3(µ-triphosphine)2(µ-NO)2(RNC)2](BF4)4

T. Tanase, M. Hamaguchi, R. Ara Begum, S. Yano and Y. Yamamoto, Chem. Commun., 1999, 745 DOI: 10.1039/A900302I

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