SCHEDULED MAINTENANCE
A series of D2-symmetric chiral trans-dioxoruthenium(VI) porphyrins can effect enantioselective epoxidation of trans-β-methylstyrene in up to 70% ee, and 76% ee is attained for the oxidation of cinnamyl chloride; the facial selection for the trans-alkenes epoxidation is explained by a ‘head-on approach’ model.
R. Zhang, W. Yu, T. Lai and C. Che, Chem. Commun., 1999, 409 DOI: 10.1039/A808776H
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