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Issue 23, 1998
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Decarboxylation of an α-amino acid coordinated to cobalt(III): kinetic stabilisation and molecular structure of a Co–C–N three-membered ring incorporated into a cobalt(III) macrocyclic ligand complex†‡

Abstract

Photochemically-induced decarboxylation of a cobalt(III) cyclam complex bearing two coordinated N-carboxymethyl pendant arms results in kinetic stabilisation of the resulting aminoalkyl three-membered Co–C–N ring, which has been characterised by an X-ray crystal structure determination.

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Chem. Commun., 1998, 2593-2594
Article type
Paper

Decarboxylation of an α-amino acid coordinated to cobalt(III): kinetic stabilisation and molecular structure of a Co–C–N three-membered ring incorporated into a cobalt(III) macrocyclic ligand complex†‡

D. M. Tonei, L. Baker, P. J. Brothers, G. R. Clark and D. C. Ware, Chem. Commun., 1998, 2593
DOI: 10.1039/A807365A

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