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Issue 12, 1998
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Cationic ruthenium allenylidene complexes as a new class of performing catalysts for ring closing metathesis

Abstract

Cationic allenylidene ruthenium complexes [Ru[double bond, length half m-dash] C[double bond, length half m-dash]C[double bond, length half m-dash]CR2(L)(Cl)(arene)]PF6 (L = PCy3, PPri3), easily prepared from RuCl2(L)(p-cymene), prop-2-yn-1-ol and NaPF6, are found to be excellent catalyst precursors for ring closing olefin metathesis.

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Article information


Chem. Commun., 1998, 1315-1316
Article type
Paper

Cationic ruthenium allenylidene complexes as a new class of performing catalysts for ring closing metathesis

A. Fürstner, A. Fürstner, M. Picquet, C. Bruneau and P. H. Dixneuf, Chem. Commun., 1998, 1315
DOI: 10.1039/A803286F

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