Issue 15, 1998

The activation of carbon disulfide by a cluster. The reaction of the µ3-CS complex [{Co(η-C5H5)}2{Fe(CO)2PPh3}(µ3-S)(µ3-CS)] with CS2

Abstract

When [{Co(η-C5H5)}2{Fe(CO)2PPh3}(µ3-S)(µ3-CS)] is refluxed in CS2 solution, it is converted to [{Co(η-C5H5)}2{Fe(CO)PPh3}(µ3-S){µ3-CSC(S)S}] which contains an unusual C2S3 bridging ligand.

Article information

Article type
Paper

Chem. Commun., 1998, 1577-1578

The activation of carbon disulfide by a cluster. The reaction of the µ3-CS complex [{Co(η-C5H5)}2{Fe(CO)2PPh3}(µ3-S)(µ3-CS)] with CS2

A. R. Manning, A. J. Palmer, A. R. Manning, J. McAdam, B. H. Robinson and J. Simpson, Chem. Commun., 1998, 1577 DOI: 10.1039/A802906G

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