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Issue 13, 1998
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Assembly based on µ4-bridging thiolate: a new type of polymeric silver(I) complex having a one dimensional chain structure

Abstract

The polymeric silver(I)–thiolate complex [{Ag84-SC2H4- NH3)6Cl6}Cl2]n has been prepared from the assembling reaction of silver chloride and 2-mercaptoethylamine hydrochloride in DMF; X-ray diffraction analysis shows the complex has a one dimensional chain structure and all the sulfur atoms of the thiolates exhibit µ4 bonding bridging four silver(I) centers.

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Article type: Paper
DOI: 10.1039/A802286K
Chem. Commun., 1998, 1389-1390

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    Assembly based on µ4-bridging thiolate: a new type of polymeric silver(I) complex having a one dimensional chain structure

    W. Su, R. Cao, J. Chen and J. Lu, Chem. Commun., 1998, 1389
    DOI: 10.1039/A802286K

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