The absorption spectrum of perhexyldecasilane shows marked temperature dependence; a two-site model, similar to the transition from a random coil to an all pseudo-trans rod conformation proposed for poly(dihexylsilylene), is proposed to explain this effect.
K. Obata, M. Kira, K. Obata and M. Kira, Chem. Commun., 1998, 1309 DOI: 10.1039/A802171F
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