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Issue 9, 1998
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Systematic synthesis of a series of hydroperoxo-, alkylperoxo- and µ-peroxo-palladium complexes supported by the hydrotris(3,5-diisopropylpyrazolyl)borate ligand (TpiPr), TpiPrPd(py)–OOX [X = PdTpiPr(py), H, But], via dehydrative condensation of a hydroxo complex, TpiPrPd(py)–OH

Abstract

A series of hydroperoxo, tert-butylperoxo and µ-peroxo complexes of palladium, TpiPrPd(py)(OOX) [X = H, But, PdTpiPr(py); TpiPr: hydrotris(3,5-diisopropylpyrazolyl)borate] is prepared by dehydrative condensation of a hydroxo complex, TpiPrPd(py)(OH), with HOOX.

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Article information


Chem. Commun., 1998, 1005-1006
Article type
Paper

Systematic synthesis of a series of hydroperoxo-, alkylperoxo- and µ-peroxo-palladium complexes supported by the hydrotris(3,5-diisopropylpyrazolyl)borate ligand (TpiPr), TpiPrPd(py)–OOX [X = PdTpiPr(py), H, But], via dehydrative condensation of a hydroxo complex, TpiPrPd(py)–OH

M. Akita, T. Miyaji and Y. Moro-oka, Chem. Commun., 1998, 1005
DOI: 10.1039/A801111G

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