Systematic synthesis of a series of hydroperoxo-, alkylperoxo- and µ-peroxo-palladium complexes supported by the hydrotris(3,5-diisopropylpyrazolyl)borate ligand (TpiPr), TpiPrPd(py)–OOX [X = PdTpiPr(py), H, But], via dehydrative condensation of a hydroxo complex, TpiPrPd(py)–OH
Abstract
A series of hydroperoxo, tert-butylperoxo and µ-peroxo complexes of palladium, TpiPrPd(py)(OOX) [X = H, But, PdTpiPr(py); TpiPr: hydrotris(3,5-diisopropylpyrazolyl)borate] is prepared by dehydrative condensation of a hydroxo complex, TpiPrPd(py)(OH), with HOOX.