Issue 16, 1997

Carbon monoxide–phosphaalkyne coupling and C–H activation of an N–Me group in the 4e-η2-phosphaalkyne complex [WF(C6H4CH2NMeCH2CH2 NMe2)(CO)(η2-P[triple bond, length as m-dash]CBut)]. Crystal and molecular structure of [WF{CH2N(CH2Ph)CH2CH2NMe 2}(CO){η4-PCBut(CO)CBu tP}]

Abstract

An unusual series of reactions involving an intermediate 4e η 2 -phosphaalkyne tungsten complex is described.

Article information

Article type
Paper

Chem. Commun., 1997, 1539-1540

Carbon monoxide–phosphaalkyne coupling and C–H activation of an N–Me group in the 4e-η2-phosphaalkyne complex [WF(C6H4CH2NMeCH2CH2 NMe2)(CO)(η2-P[triple bond, length as m-dash]CBut)]. Crystal and molecular structure of [WF{CH2N(CH2Ph)CH2CH2NMe 2}(CO){η4-PCBut(CO)CBu tP}]

M. Helena A. Benvenutti, P. B. Hitchcock, J. L. Kiplinger, J. F. Nixon and T. G. Richmond, Chem. Commun., 1997, 1539 DOI: 10.1039/A703303F

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