Issue 15, 1997

Preparation of 5-trimethylsilyl-1,3-phenylenebis[diazo(4-pyridyl)methane] and magnetic properties of its 1:1 copper(ii) complex after photolysis

Abstract

Photolysis of a paramagnetic 1:1 complex of copper(II) with 5-trimethylsilyl-1,3-phenylenebis[diazo(4-pyridyl)methane] produces a ferromagnetic chain consisting of an alternating array of 3d spins of Cu II and 2p spins of the quintet dicarbenes.

Article information

Article type
Paper

Chem. Commun., 1997, 1359-1360

Preparation of 5-trimethylsilyl-1,3-phenylenebis[diazo(4-pyridyl)methane] and magnetic properties of its 1:1 copper(ii) complex after photolysis

S. Karasawa, M. Tanaka, N. Koga and H. Iwamura, Chem. Commun., 1997, 1359 DOI: 10.1039/A702168B

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