Jump to main content
Jump to site search

Issue 5, 1997
Previous Article Next Article

Control and applications of remote asymmetric induction using allylmetal reagents

Abstract

Treatment of hydroxy- and alkoxy-substituted allylstannanes with tin(IV) halides effects transmetallation and the stereoselective formation of allyltin trihalides. These react with aldehydes and imines derived from glyoxylates with useful levels of remote asymmetric induction. Aspects of this chemistry are discussed, together with the conversion of the products into tetrahydrofurans and dihydropyrans.

Back to tab navigation

Article type: Paper
DOI: 10.1039/A603881F
Chem. Commun., 1997, 411-418

  •   Request permissions

    Control and applications of remote asymmetric induction using allylmetal reagents

    E. J. Thomas, Chem. Commun., 1997, 411
    DOI: 10.1039/A603881F

Search articles by author

Spotlight

Advertisements