Tetrahedral pentaerythritol tetra(3,4-dialkoxybenzoates) and tetra(3,4,5-trialkoxybenzoates) can display columnar liquid-crystalline phases despite the fact that they are neither disc-like nor amphiphilic.
A. Pegenau, P. Göring and C. Tschierske, Chem. Commun., 1996, 2563 DOI: 10.1039/CC9960002563
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