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Issue 22, 1996
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Sequential homogenous catalysis. Catalytic formation of allylic and β-keto silyl ethers from dihydrosilanes and the corresponding alcohols followed by intramolecular hydrosilation

Abstract

The catalyst, [Rh(Ph2PCH2CH2PPH2)]+ engages in a consecutive catalytic sequence where allylic alcohols, β-keto alcohols and α,β-unsaturated aldehydes in the presence of dihydrosilanes are first converted to the corresponding monohydrosilyl ethers, which are then cyclized.

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Article type: Paper
DOI: 10.1039/CC9960002561
Chem. Commun., 1996, 2561-2562

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    Sequential homogenous catalysis. Catalytic formation of allylic and β-keto silyl ethers from dihydrosilanes and the corresponding alcohols followed by intramolecular hydrosilation

    X. Wang, W. W. Ellis and B. Bosnich, Chem. Commun., 1996, 2561
    DOI: 10.1039/CC9960002561

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