Optical dσ* metal-to-ligand charge transfer of [Re2Br2(CO)6(Se2Ph2)]

Horst Kunkely; Arnd Vogler

doi:10.1039/CC9960002519

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Optical d_σ* metal-to-ligand charge transfer of [Re₂Br₂(CO)₆(Se₂Ph₂)]

Horst Kunkely and Arnd Vogler

Abstract

The binuclear complex [Re₂Br₂(CO)₆(Se₂Ph₂)] shows an absorption at λ_max= 434 nm (in CH₂Cl₂) which is assigned to a MLCT (metal-to-ligand charge transfer) transition from Re^I to the σ*(Se–Se) orbital of the bridging diphenyl diselenide ligand.

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DOI: https://doi.org/10.1039/CC9960002519
Article type: Paper

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Chem. Commun., 1996, 2519-2520

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Optical d_σ* metal-to-ligand charge transfer of [Re₂Br₂(CO)₆(Se₂Ph₂)]

H. Kunkely and A. Vogler, Chem. Commun., 1996, 2519 DOI: 10.1039/CC9960002519

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Chemical Communications

Optical d_σ* metal-to-ligand charge transfer of [Re₂Br₂(CO)₆(Se₂Ph₂)]

Abstract

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Optical d_σ* metal-to-ligand charge transfer of [Re₂Br₂(CO)₆(Se₂Ph₂)]

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