Issue 21, 1996
From the journal:

Chemical Communications

[Pt{4,4′-(NO2)2-bipy}Cl2]2–[4,4′-(NO2)2-bipy = 4,4′-dinitro-2,2′-bipyridine]: an EPR-active ‘18 electron’ platinum complex

Eric J. L. McInnes,   Alan J. Welch  and  Lesley J. Yellowlees  

Abstract

The complex [Pt{4,4′-(NO2)2-bipy}Cl2] undergoes four consecutive one-electron reductions, with a very small E1–E2 separation of 180 mV and both the mono- and di-reduction products can be electrochemically generated giving EPR-active solutions: thus [Pt{4,4′-(NO2)2-bipy}Cl2] has a nearly degenerate pair of predominantly ligand-based π* orbitals.

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Article information

DOI
https://doi.org/10.1039/CC9960002393
Article type
Paper

Chem. Commun., 1996, 2393-2394

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[Pt{4,4′-(NO2)2-bipy}Cl2]2–[4,4′-(NO2)2-bipy = 4,4′-dinitro-2,2′-bipyridine]: an EPR-active ‘18 electron’ platinum complex

E. J. L. McInnes, A. J. Welch and L. J. Yellowlees, Chem. Commun., 1996, 2393 DOI: 10.1039/CC9960002393

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