Issue 20, 1996

Niobium pentachloride-mediated novel homologation reactions using α-trialkylstannylmethyl-β-keto esters

Abstract

In the presence of niobium pentachloride (NbCl5), an α-trialkylstannylmethyl-β-keto ester is homologated to the corresponding γ-keto ester in good yield; the reaction mechanism is discussed.

Article information

Article type
Paper

Chem. Commun., 1996, 2353-2354

Niobium pentachloride-mediated novel homologation reactions using α-trialkylstannylmethyl-β-keto esters

M. Yamamoto, M. Nakazawa, K. Kishikawa and S. Kohmoto, Chem. Commun., 1996, 2353 DOI: 10.1039/CC9960002353

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