SCHEDULED MAINTENANCE
Intramolecular N–H insertion reactions of α-diazocarbonyl substrates are catalysed by rhodium(II) carboxylates with catalyst-dependent competition with C–H insertion and β-elimination; asymmetric N–H insertion leading to a pipecolic acid derivative with ee up to 45% is achieved using chiral catalysts.
C. F. García, M. A. McKervey and T. Ye, Chem. Commun., 1996, 1465 DOI: 10.1039/CC9960001465
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