Issue 7, 1996

Chain–ring isomerism vs. carbon–carbon coupling on two(tetracarbonyliron)-γ-ketoesters: cis-[Fe(COR)(COCOR′)(CO)4](R = Me, R′= OMe; R = OMe; R′= Me)

Abstract

Ferra-γ-ketoesters 1 and 2 induce thermally either a carbon–carbon coupling process or a chain–ring isomerization; the orientation of the reaction likely depends on the proximity of the ester group to the metal centre.

Article information

Article type
Paper

Chem. Commun., 1996, 857-858

Chain–ring isomerism vs. carbon–carbon coupling on two(tetracarbonyliron)-γ-ketoesters: cis-[Fe(COR)(COCOR′)(CO)4](R = Me, R′= OMe; R = OMe; R′= Me)

M. Sellin, D. Luart, J. Salaün, P. Laurent, L. Toupet and H. des Abbayes, Chem. Commun., 1996, 857 DOI: 10.1039/CC9960000857

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