The first air-stable, cationic rhodadicarborane complex, [3-(MeCN)-3,3-(PPh2Me)2-3,1,2-closo-RhC2B9H11][SbF6] 1, which does not contain a ‘charge-compensated’ carborane ligand is synthesised and structurally characterised by X-ray crystallography and spectroscopic techniques (IR and NMR).
G. Ferguson, J. Pollock, P. A. McEneaney, D. P. O'Connell, T. R. Spalding, J. F. Gallagher, R. Maciás and J. D. Kennedy, Chem. Commun., 1996, 679 DOI: 10.1039/CC9960000679
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