Free radical cyclization of cyclohexyl 8-iodo-nona-2,8-dienoate in the presence of a chiral aluminium reagent, prepared from (R)-3,3′-bis(triphenylsilyl)-1,1′-bi-2-naphthol and Me3Al, gives optically active 2-(2-methylenecyclopentyl)acetate in 63% yield and 46% ee.
M. Nishida, H. Hayashi, A. Nishida and N. Kawahara, Chem. Commun., 1996, 579 DOI: 10.1039/CC9960000579
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