Issue 2, 1996

Serendipitous synthesis of a novel cobalt(III) porphyrin phosphoryl complex

Abstract

A novel complex [bis(dimethylamino)phosphoryl](5,10,15,20-tetraphenylporphyrinato)cobalt(III) 1 is synthesized serendipitously by the reaction of [CoIII(tpp)Br] with Me3SiLi (MeLi–Si2Me6–HMPA) at –78 °C in thf and its structure is characterized by a single-crystal X-ray study.

Article information

Article type
Paper

Chem. Commun., 1996, 173-174

Serendipitous synthesis of a novel cobalt(III) porphyrin phosphoryl complex

A. K.-S. Tse, R. Wang, T. C. W. Mak and K. S. Chan, Chem. Commun., 1996, 173 DOI: 10.1039/CC9960000173

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