Issue 2, 1996

Formation of mononuclear nitrido complexes of chromium(VI) and molybdenum(VI); syntheses and X-ray crystal structures of N[triple bond, length half m-dash]Cr(OBut)3 and N[triple bond, length half m-dash]Mo(OSiMe3)3(py)

Abstract

Mononuclear nitrido complexes of Cr and Mo, N[triple bond, length half m-dash]Cr(OBut)3 and N[triple bond, length half m-dash]Mo(OSiMe3)3(py), are synthesized; the chromium complex has an idealized C3ν symmetry while the molybdenum complex has a distorted square-pyramidal geometry with the nitrido ligand at apical position; the N–Cr distance is 1.538(5)Å while the average N–Mo distance is 1.627 Å.

Article information

Article type
Paper

Chem. Commun., 1996, 139-140

Formation of mononuclear nitrido complexes of chromium(VI) and molybdenum(VI); syntheses and X-ray crystal structures of N[triple bond, length half m-dash]Cr(OBut)3 and N[triple bond, length half m-dash]Mo(OSiMe3)3(py)

H. Chiu, Y. Chen, S. Chuang, J. Jen, G. Lee and S. Peng, Chem. Commun., 1996, 139 DOI: 10.1039/CC9960000139

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