Issue 20, 1995
From the journal:

Journal of the Chemical Society, Chemical Communications

The synthesis and single-crystal X-ray structure of the first example of a tridentate, di-orthometallated triphenyl phosphite complex

Robin B. Bedford,   Penny A. Chaloner  and  Peter B. Hitchcock  

Abstract

Reaction of [Ir(cod)(py)2][PF6] with triphenyl phosphite leads to the previously reported complex [Ir(cod){P(OC6H4)(OPh)2{P(OPh)3}], but reaction of [Ir(cod){P(OPh)3}Cl] with methyllithium and subsequent treatment with methanol yields the tridentate di-orthometallated complex [IrH(cod){P(OC6H4)2(OPh)}].

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Article information

DOI
https://doi.org/10.1039/C39950002049
Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 2049-2050

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The synthesis and single-crystal X-ray structure of the first example of a tridentate, di-orthometallated triphenyl phosphite complex

R. B. Bedford, P. A. Chaloner and P. B. Hitchcock, J. Chem. Soc., Chem. Commun., 1995, 2049 DOI: 10.1039/C39950002049

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