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Issue 19, 1995
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New strategy for the synthesis of the taxane diterpenes: formation of the A-ring via nitro-aldol and aldol reactions

Abstract

The nitro-aldehyde /β readily cyclizes to form the A-ring of taxol in quantitative yield; further elaboration of the α,β-unsaturated nitro compound 12 gave the enone 16 and the 13α alcohol 17 respectively.

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Article type: Paper
DOI: 10.1039/C39950001933
J. Chem. Soc., Chem. Commun., 1995, 1933-1934

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    New strategy for the synthesis of the taxane diterpenes: formation of the A-ring via nitro-aldol and aldol reactions

    P. Magnus and P. Pye, J. Chem. Soc., Chem. Commun., 1995, 1933
    DOI: 10.1039/C39950001933

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