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Issue 18, 1995
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An unexpected reaction between B(C6F5)3 and [Fe(η5-C5H5)(CO)2Me] gives {[Fe-σ-C6F4(2-C(O)Me)](η5-C5H5)(CO)}

Abstract

The reaction between B(C6F5)3 and [Fe(η5-C5H5)(CO)2Me] gives the unexpected product {[[graphic omitted])Me)](η5-C5H5)(CO)}, which reacts with the donor molecules L, where L = PMe3, PPh3, or ButNC, giving {[[graphic omitted]O)Me)](η5-C5H5)(L)}.

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Article type: Paper
DOI: 10.1039/C39950001853
J. Chem. Soc., Chem. Commun., 1995, 1853-1854

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    An unexpected reaction between B(C6F5)3 and [Fe(η5-C5H5)(CO)2Me] gives {[Fe-σ-C6F4(2-C(O)Me)](η5-C5H5)(CO)}

    M. L. H. Green, J. Haggitt and C. P. Mehnert, J. Chem. Soc., Chem. Commun., 1995, 1853
    DOI: 10.1039/C39950001853

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