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Issue 15, 1995
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Selective hydrogenations of dienes and oiefins by [W2(OCH2But)6(py)2]

Abstract

Hydrocarbon solutions of [W2(OCH2But)6(py)2] in the presence of H2(3 atm, 23 °C) hydrogenate linear 1,3-dienes to 3-enes, 1,3- and 1,5-cyclooctadiene to cyclooctene, 1,3-cyclohexadiene to cyclohexene, cyclopentene to cyclopentane, and norbornene to norbornane, but do not hydrogenate α- and internal olefins to alkanes, or internal conjugated or unconjugated dienes.

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Article information


J. Chem. Soc., Chem. Commun., 1995, 1599-1600
Article type
Paper

Selective hydrogenations of dienes and oiefins by [W2(OCH2But)6(py)2]

J. T. Barry and M. H. Chisholm, J. Chem. Soc., Chem. Commun., 1995, 1599
DOI: 10.1039/C39950001599

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