Jump to main content
Jump to site search

Issue 15, 1995
Previous Article Next Article

Site-specific ligand variation in manganese–oxide cubane complexes, and unusual magnetic relaxation effects in [Mn4O4X(OAc)3(dbm)3](X = N3, OCN Hdbm = dibenzoylmethane)

Abstract

Treatment of [Mr4O2(OAc)6(py)2(dbm)2]1(py = pyridine, Hdbm = dibenzoylmethane) in hot MeCN with Me3SiX (X = N3, OCN ) yields [Mn4O3X(OAc)3(dbm)3] containing extremely rare η1, µ3-N3 or -OCN groups; alternating-current magnetic susceptibility studies reveal unusual magnetic relaxation effects and indicate these species to be the newest and smallest examples yet of truly molecular magnets.

Back to tab navigation

Article information


J. Chem. Soc., Chem. Commun., 1995, 1591-1593
Article type
Paper

Site-specific ligand variation in manganese–oxide cubane complexes, and unusual magnetic relaxation effects in [Mn4O4X(OAc)3(dbm)3](X = N3, OCN Hdbm = dibenzoylmethane)

M. W. Wemple, D. M. Adams, K. S. Hagen, K. Folting, D. N. Hendrickson and G. Christou, J. Chem. Soc., Chem. Commun., 1995, 1591
DOI: 10.1039/C39950001591

Search articles by author

Spotlight

Advertisements