Reaction of 1,2,3-triarylbenzo[b]thiophenium salts with alkoxide anions results in the exclusive formation of (Z) alkoxy-substituted alkenes, indicating that the nucleophilic ring-opening reaction proceeds with complete retention of configuration.
T. Kitamura, M. Miyaji, S. Soda and H. Taniguchi, J. Chem. Soc., Chem. Commun., 1995, 1375 DOI: 10.1039/C39950001375
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