Rearrangement of 1,2-diphenylhydrazine occurs exclusively to o-semidine in the presence of a rhodium catalyst with o-semidine bonding to rhodium(I) as a bidentate ligand.
C. J. Davies, B. T. Heaton and C. Jacob, J. Chem. Soc., Chem. Commun., 1995, 1177 DOI: 10.1039/C39950001177
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