Issue 8, 1995

Aziridination of alkenes using 3-acetoxyaminoquinazolin-4-(3H)ones in the presence of tertiary amines: evidence for an azaimide (N-nitrene) intermediate

Abstract

Solutions of the triethylammonium imide 8, formed from triethylamine and 3-acetoxyaminoquinazolinone 4, react with alkenes at –30 °C to give aziridines; the reactivity of the aziridinating intermediate is consistent with its formulation as an azaimide (N-nitrene).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 819-820

Aziridination of alkenes using 3-acetoxyaminoquinazolin-4-(3H)ones in the presence of tertiary amines: evidence for an azaimide (N-nitrene) intermediate

R. S. Atkinson and E. Barker, J. Chem. Soc., Chem. Commun., 1995, 819 DOI: 10.1039/C39950000819

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