SCHEDULED MAINTENANCE
The mixture of two isomers of the new complex Os(H)(CO)(quS)(PPh3)23 reacts with HBF4·Et2O at –80 °C to form the complexes [Os(η2-H2)(CO)(quS)(PPh3)2]+, with dihydrogen trans to sulfur 4a or nitrogen 4b along with tautomeric thiol complexes [Os(H)(CO)(quSH)(PPh3)2]+4c,d; the tautomeric equilibria shift with temperature.
M. Schlaf and R. H. Morris, J. Chem. Soc., Chem. Commun., 1995, 625 DOI: 10.1039/C39950000625
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