Issue 21, 1994
From the journal:

Journal of the Chemical Society, Chemical Communications

P–H-functionalized ylide–carbene complexes: synthesis of [(CO)5M[double bond, length half m-dash]C(OEt)CH[double bond, length half m-dash]P(NPri2)2H](M = Cr, W) and structure of the chromium derivative

Rainer Streubel,   Markus Hobbold,   Jörg Jeske  and  Peter G. Jones  

Abstract

[(CO)5M[double bond, length half m-dash]C(OEt)CH2Li]1a,b(M: a, Cr; b, W) react with CIP(NPri2)22 to yield the P–H-functionalized ylide–carbene complexes 4a,bvia transiently formed [α-(phosphino)alkyl]carbene complexes 3a,b; compounds 4a,b are characterized by NMR spectroscopy (13C, 31P) and complex 4a by single crystal X-ray diffraction.

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Article information

DOI
https://doi.org/10.1039/C39940002457
Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 2457-2458

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P–H-functionalized ylide–carbene complexes: synthesis of [(CO)5M[double bond, length half m-dash]C(OEt)CH[double bond, length half m-dash]P(NPri2)2H](M = Cr, W) and structure of the chromium derivative

R. Streubel, M. Hobbold, J. Jeske and P. G. Jones, J. Chem. Soc., Chem. Commun., 1994, 2457 DOI: 10.1039/C39940002457

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