The reaction of a lithiated phosphine–borane or a phosphinite borane with C60 followed by removal of the BH3 group affords a phosphine or a phosphinite bearing a fullerene substituent, which undergoes complexation with BH3 and PtCl2 selectively on the phosphorus atom with 1 : 1 and 2 : 1 stoichiometry.
S. Yamago, M. Yanagawa and E. Nakamura, J. Chem. Soc., Chem. Commun., 1994, 2093 DOI: 10.1039/C39940002093
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