Issue 14, 1994

Enantiomeric epoxidation of 4-chlorostyrene with H2O2 catalysed by robust chloro manganese(III)meso-5,10,15,20-tetrakis [2-chloro-6-(2,3,4,6-tetraacetyl-O-β-glucosyl)phenyl] porphyrins

Abstract

Three new chiral porphyrins bearing chloro and glucosyl groups are obtained by Lindsey's method; their chloro manganese(III) complexes are robust catalysts for the asymmetric epoxidation of 4-chlorostyrene with diluted hydrogen peroxide.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 1697-1698

Enantiomeric epoxidation of 4-chlorostyrene with H2O2 catalysed by robust chloro manganese(III)meso-5,10,15,20-tetrakis [2-chloro-6-(2,3,4,6-tetraacetyl-O-β-glucosyl)phenyl] porphyrins

S. Vilain, P. Maillard and M. Momenteau, J. Chem. Soc., Chem. Commun., 1994, 1697 DOI: 10.1039/C39940001697

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