Issue 13, 1994

Short synthesis of the dynemicin core structure: unusual bridgehead enolate reactivity

Abstract

The dynemicin core azabicyclo[7.3.1]enediyne 2 is readily synthesized in five steps from the quinolines 9 or 13; the chemistry of the core enediyne is dominated by its ready enolization.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 1543-1544

Short synthesis of the dynemicin core structure: unusual bridgehead enolate reactivity

P. Magnus, D. Parry, T. Iliadis, S. A. Eisenbeis and R. A. Fairhurst, J. Chem. Soc., Chem. Commun., 1994, 1543 DOI: 10.1039/C39940001543

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