Hydrolysis of the P–OAr bond in dimethyl aryl phosphates is catalysed by fluoride ion due to the fast formation of intermediate phosphorofluoridate; LiF shows a much weaker catalytic effect than other alkali metal and tetramethylammonium fluoride salts.
M. Mentz, A. M. Modro and T. A. Modro, J. Chem. Soc., Chem. Commun., 1994, 1537 DOI: 10.1039/C39940001537
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