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Issue 1, 1994
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Silylene complexes from a stable silylene and metal carbonyls: synthesis and structure of [Ni{(ButN–CH[double bond, length half m-dash]CH–NBut)Si}2(CO)2], a donor-free bis-silylene complex

Abstract

[Ni(LSi)2(CO)2]3; the first silylene complex of nickel, has been obtained from the stable silylene 1,3-di-tert-2,3-dihydro-1H-1,3,2-diazasilol-2-ylidene (LSi)1 and tetracarbonylnickel; complex 3 was characterized by single crystal X-ray diffraction and NMR spectroscopy (1H, 13C, 29Si).

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J. Chem. Soc., Chem. Commun., 1994, 33-34
Article type
Paper

Silylene complexes from a stable silylene and metal carbonyls: synthesis and structure of [Ni{(ButN–CH[double bond, length half m-dash]CH–NBut)Si}2(CO)2], a donor-free bis-silylene complex

M. Denk, R. K. Hayashi and R. West, J. Chem. Soc., Chem. Commun., 1994, 33
DOI: 10.1039/C39940000033

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