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Issue 1, 1994
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The preparation and X-ray crystal structure of the first metal–1,3,2,4-dithiadiazolylium salt, [Hg(CNSNS)2][AsF6]2, a transfer agent for the dithiadiazolylium ring

Abstract

The reaction of two equivalents of [SNS][AsF6] with Hg(CN)2 yields [Hg([graphic omitted])2][AsF6]21, the first example of a dithiadiazolylium ring bonded to a metal centre via the carbon; the reaction of 1 with iodine and bromine gave the hexafluoroarsenates(V) of [I–[graphic omitted]]+ and previously unreported [Br–[graphic omitted]]+, thereby demonstrating the potential of 1 as a transfer reagent for the dithiadiazolylium cation.

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Article information


J. Chem. Soc., Chem. Commun., 1994, 29-30
Article type
Paper

The preparation and X-ray crystal structure of the first metal–1,3,2,4-dithiadiazolylium salt, [Hg(CNSNS)2][AsF6]2, a transfer agent for the dithiadiazolylium ring

A. J. Banister, I. Lavender, S. E. Lawrence, J. M. Rawson and W. Clegg, J. Chem. Soc., Chem. Commun., 1994, 29
DOI: 10.1039/C39940000029

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