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Issue 19, 1993
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Double sulfur–carbon bond cleavage of a dithiocarbamate ligand at a molybdenum(VI) centre; synthesis and X-ray structure of the disulfur complex [Mo(NPh)(S2)(edtc)2](edtc = S2CNEt2)

Abstract

Reaction of 1 equiv. of PhNCO with [MoO2(edtc)2] leads to the isolation of [Mo(NPh)(S2)(edtc)2] formed as a result of oxo substitution and a double sulfur-carbon bond cleavage of the dithiocarbamate; a second product is dimeric [MoO(edtc)(µ-NPh)]2.

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Article information


J. Chem. Soc., Chem. Commun., 1993, 1524-1525
Article type
Paper

Double sulfur–carbon bond cleavage of a dithiocarbamate ligand at a molybdenum(VI) centre; synthesis and X-ray structure of the disulfur complex [Mo(NPh)(S2)(edtc)2](edtc = S2CNEt2)

T. A. Coffey, G. D. Forster and G. Hogarth, J. Chem. Soc., Chem. Commun., 1993, 1524
DOI: 10.1039/C39930001524

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