195 Pt magic-angle spinning (MAS) NMR spectra of the monomeric complexes Pt(en)Cl2 and Pt(en)Cl4 and of the linear-chain complex [Pt(en)Cl2][Pt(en)Cl4] show that the PtII and PtIV sites in the mixed-valence complex have isotropic chemical shifts and shielding anisotropies that are surprisingly similar to those of their monomeric constituents.
E. J. W. Austin, P. J. Barrie and R. J. H. Clark, J. Chem. Soc., Chem. Commun., 1993, 1404 DOI: 10.1039/C39930001404
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