Issue 15, 1993
From the journal:

Journal of the Chemical Society, Chemical Communications

Activation of H2 by chlorocarbonylbis(trimethylphosphine)rhodium(I) labilizes CO and produces the new binuclear complex H(Cl)Rh(PMe3)2(µ-H)(µ-Cl)RH(PMe3)(CO)

Simon B. Duckett,   Richard Eisenberg  and  Alan S. Goldman  

Abstract

The oxidative addition of H2 to [RhCl(CO)(PMe3)2] is followed using NMR spectroscopy in conjunction with para-enriched hydrogen and leads to CO labilization and formation of an unusual binuclear complex.

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Article information

DOI
https://doi.org/10.1039/C39930001185
Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 1185-1187

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Activation of H2 by chlorocarbonylbis(trimethylphosphine)rhodium(I) labilizes CO and produces the new binuclear complex H(Cl)Rh(PMe3)2(µ-H)(µ-Cl)RH(PMe3)(CO)

S. B. Duckett, R. Eisenberg and A. S. Goldman, J. Chem. Soc., Chem. Commun., 1993, 1185 DOI: 10.1039/C39930001185

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